Product ID:PURGEABLE HALOCARBONS KIT 601-S, 48769 (SUP
MSDS Date:05/27/1992
FSC:6630
NIIN:00N038707
Kit Part:Y
MSDS Number: BRFHM

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 0.02%

OSHA PEL 350 PPM;450 PPM STEL

ACGIH TLV: 350 PPM;450 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL,RAT) 5628 MG/KG.

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.98%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LABORATORY
ANIMALS & COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS
(E.G., EPINEPHRINE) MAY BE CONTRAINDIC ATED EXCEPT FOR
LIFE-SUSTAINING USES INHUMANS ACUTELY OR CHRONICALLY EXPOSED TO
CHLOROCARBONS . (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. HEADACHE, NAUSEA, GASTROINTESTINAL DISTURBANCES,
BLINDNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH W/WATER FOR AT LST 15 MINS. CONT MD. SKIN:FLUSH
W/LG VOLS OF WATER. INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS,
GIVE ARTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERSO N. NEVER TRY TO MAKE UNCON PERSON VOMIT. GIVE 2 TBSPS
OF BAKING SODA IN GLASS OF WATER, PRESS FINGERS TO BACK OF TONGUE
TO INDUCE VOMIT. IMMED CONT MD.

Flash Point:50.0F,10.0C
Lower Limits:6%
Upper Limits:36.5%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE .

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN COOL, DRY
LOCATION. KEEP AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION
SOURCES. AVOID EYE/SKIN CONTACT. AVOID BRTHG VAPS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN A WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:1,1,1-TRICHLOROETHANE PART M.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79 (H*2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100%
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Hazardous Decomposition Products:HCL, PHOSGENE .

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE OR LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.